SIST EN 10184:2006

SLOVENSKI STANDARD
SIST EN 10184:2006
01-maj-2006
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SIST EN 10184:1997/AC1:1997
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Chemical analysis of ferrous materials - Determination of phosphorus in non-alloyed
steels and irons - Molybdenum blue spectrophotometric method
Chemische Analyse von Eisenwerkstoffen - Bestimmung von Phosphor in unlegierten
Stählen und Eisen - Spektralphotometrisches Verfahren über Molybdänblau
Analyse chimique des matériaux sidérurgiques - Dosage du phosphore dans les aciers
et fontes non alliés - Méthode par spectrophotométrie d´absorption moléculaire
Ta slovenski standard je istoveten z: EN 10184:2006
ICS:
77.040.30 Kemijska analiza kovin Chemical analysis of metals
SIST EN 10184:2006 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN 10184:2006

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SIST EN 10184:2006
EUROPEAN STANDARD
EN 10184
NORME EUROPÉENNE
EUROPÄISCHE NORM
February 2006
ICS 77.040.30 Supersedes EN 10184:1989
English Version
Chemical analysis of ferrous materials - Determination of
phosphorus in non-alloyed steels and irons - Molybdenum blue
spectrophotometric method
Analyse chimique des matériaux sidérurgiques - Chemische Analyse von Eisenwerkstoffen - Bestimmung
Détermination du phosphore dans les aciers et fontes non von Phosphor in unlegierten Stählen und Eisen -
alliés - Méthode par spectrophotométrie au bleu de Spektralphotometrisches Verfahren über Molybdänblau
molybdène
This European Standard was approved by CEN on 30 December 2005.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,
Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2006 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 10184:2006: E
worldwide for CEN national Members.

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SIST EN 10184:2006
EN 10184:2006 (E)
Contents Page
Foreword.3
1 Scope .4
2 Normative references .4
3 Principle.4
4 Reagents.4
5 Apparatus .6
6 Sampling.6
7 Procedure .6
8 Expression of results .8
9 Note .9
10 Test report .9
Annex A (informative) Precision data.10
Bibliography .11

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SIST EN 10184:2006
EN 10184:2006 (E)
Foreword
This European Standard (EN 10184:2006) has been prepared by Technical Committee ECISS/TC 20
“Methods of chemical analysis of ferrous products”, the secretariat of which is held by SIS.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by August 2006, and conflicting national standards shall be withdrawn
at the latest by August 2006.
This European Standard supersedes EN 10184:1989.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic,
Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden,
Switzerland and United Kingdom.
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SIST EN 10184:2006
EN 10184:2006 (E)
1 Scope
This European Standard specifies a method for the molybdenum blue spectrophotometric determination of
phosphorus in non-alloyed steels and irons.
The method is applicable to non-alloyed steels and irons with phosphorus contents from 0,005 % to 0,25 %
(m/m).
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.
EN ISO 14284, Steel and iron — Sampling and preparation of samples for the determination of chemical
composition (ISO 14284:1996)
3 Principle
Dissolution of a test portion in nitric and hydrochloric acids and controlled addition of perchloric acid.
Formation of the phosphomolybdate complex after removal of silicon and arsenic and reduction with
hydrazine sulphate to molybdenum blue.
Spectrophotometric measurement of the blue complex at a wavelength of 680 nm or 825 nm.
4 Reagents
4.1 General
During the analysis, unless otherwise stated, only reagents of recognized analytical grade shall be used and
only distilled water or water of equivalent purity.
Blank tests shall verify that the relevant reagents are free from phosphorus. Whenever necessary, the
results shall be corrected accordingly. Grades giving high blank values are unsuitable and should be
discarded.
4.2 Hydrochloric acid
ρ about 1,19 g/ml.
4.3 Nitric acid
ρ about 1,40 g/ml.
4.4 Perchloric acid
ρ about 1,67 g/ml.
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SIST EN 10184:2006
EN 10184:2006 (E)
4.5 Hydrofluoric acid
ρ about 1,13 g/ml, diluted 1 + 9.
4.6 Hydrobromic acid
ρ about 1,47 g/ml, diluted 1 + 1.
4.7 Perchloric acid
ρ about 1,67 g/ml, diluted 42 + 58.
420 ml perchloric acid (4.4) shall be carefully poured into 400 ml of water. Swirl, cool, transfer to a 1000 ml
volumetric flask. Dilute to the mark with water and mix.
4.8 Sulphuric acid
ρ about 1,84 g/ml, diluted 3 + 37.
37,5 ml sulphuric acid (ρ about 1,84 g/ml) shall be carefully poured into 300 ml water. Swirl, cool and
transfer to a 500 ml volumetric flask. Dilute to the mark with water and mix.
4.9 Sodium metabisulphite
100 g/l solution.
100 g of dry sodium metabisulphite (Na S O ) shall be dissolved in 500 ml of warm water, filter and collect
2 2 5
the filtrate in a 1000 ml volumetric flask. Cool, dilute to the mark with water and mix.
4.10 Hydrazine sulphate
1,5 g/l solution to be prepared immediately before use.
4.11 Ammonium molybdate
20 g/l solution.
Dissolve 20 g of ammonium molybdate [(NH ) Mo O 4H O] in about 100 ml of diluted sulphuric acid (4.8).
4 6 7 24 2
Dilute to around 500 ml with water. Carefully pour 300 ml of sulphuric acid (4.8) into this solution. Swirl, cool
and transfer to a 1000 ml volumetric flask. Dilute to the mark with water and mix.
4.12 Molybdate reagent
Prepare immediately before use the following mixture:
Add, in order, to a 1000 ml volumetric flask, swirling between additions:
 500 ml of water;
 250 ml of molybdate solution (4.11);
 100 ml of hydrazine sulphate solution (4.10).
Dilute to the mark with water and mix.
...