SIST EN 14719:2005

SLOVENSKI STANDARD
SIST EN 14719:2005
01-december-2005
9ODNQLQHSDSLULQNDUWRQ±'RORþHYDQMHGLLVRSURSLOQDIWDOHQD',31SULHNVWUDNFLMLV
WRSLORP
Pulp, paper and board - Determination of the Diisopropylnaphthalene (DIPN) content by
solvent extraction
Faserstoff, Papier und Karton - Bestimmung des Gehaltes an Diisopropylnaphthalin
(DIPN) mittels Lösemittelextraktion
Pâtes, papiers et cartons - Détermination de la teneur en diisopropylnaphtalene (DIPN)
par extraction au solvant
Ta slovenski standard je istoveten z: EN 14719:2005
ICS:
85.040 Vlaknine Pulps
85.060 Papir, karton in lepenka Paper and board
SIST EN 14719:2005 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------

SIST EN 14719:2005

---------------------- Page: 2 ----------------------

SIST EN 14719:2005
EUROPEAN STANDARD
EN 14719
NORME EUROPÉENNE
EUROPÄISCHE NORM
August 2005
ICS 85.040; 85.060
English version
Pulp, paper and board - Determination of the
Diisopropylnaphthalene (DIPN) content by solvent extraction
Pâtes, papiers et cartons - Détermination de la teneur en Faserstoff, Papier und Karton - Bestimmung des Gehaltes
diisopropylnaphtalène (DIPN) par extraction au solvant an Diisopropylnaphthalin (DIPN) mittels
Lösemittelextraktion
This European Standard was approved by CEN on 27 June 2005.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,
Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2005 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 14719:2005: E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------

SIST EN 14719:2005
EN 14719:2005 (E)
Contents
Foreword .3
1 Scope.4
2 Principle.4
3 Reagents.4
3.1 General.4
3.2 Standards.4
3.2.1 Diisopropylnaphthalene (DIPN) (technical mixture of isomers) .4
3.2.2 Diethylnaphthalene (DEN), with a purity of 97 % or more.4
3.3 Chemicals, Acetone.4

3.4 Calibration stock solutions.4
3.5 Internal standard stock solution.5
4 Apparatus and auxiliary aids .5
4.1 Gas chromatograph.5
4.2 Gas chromatograph analytical capillary column.5
4.3 Ultrasonic bath.6
4.4 Microsyringes, 100 µl, 250 µl.6
4.5 Graduated pipettes, 1 ml, 2 ml, 10 ml .6
4.6 40 ml screw top vials, with PTFE (polytetrafluorethylene) lined septa .6
5 Sampling.6
6 Preparation of test pieces .6
7 Calibration.6
7.1 Calibration standards.6
7.1.1 General.6
7.1.2 Calibration A.6
7.1.3 Calibration B.6
7.2 Blank value.7
7.3 Control standard.7

8 Procedure.7
8.1 GC-MS analysis.7
8.2 Calibration.7
8.3 Test piece analysis .7
8.3.1 Test piece extracts.7
8.3.2 Determination of DIPN.7
8.4 Evaluation of data .7
8.4.1 Interferences.7
8.4.2 Determination of the DIPN concentration in the test pieces.7
8.4.3 Calculation of the DIPN content in the paper.8
9 Precision.9
10 Test report.9
Bibliography.10


2

---------------------- Page: 4 ----------------------

SIST EN 14719:2005
EN 14719:2005 (E)
Foreword
This European Standard (EN 14719:2005) has been prepared by Technical Committee CEN/TC 172 "Pulp, paper
and board", the secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an identical text or
by endorsement, at the latest by February 2006, and conflicting national standards shall be withdrawn at the latest
by February 2006.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark,
Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
3

---------------------- Page: 5 ----------------------

SIST EN 14719:2005
EN 14719:2005 (E)

1 Scope
This European Standard describes a method for the determination of the content of diisopropylnaphthalene (DIPN)
in paper, board and pulp by solvent extraction. The content of diisopropylnaphthalene (DIPN) is expressed as mg
of total diisopropylnaphthalene DIPN isomers per kilogram of paper, board or pulp. This test method is appropriate
for the quantitative determination of the content of diisopropylnaphthalene (DIPN) with a limit of determination of
about 0,6 mg/kg.
2 Principle
The content of total diisopropylnaphthalene (DIPN) is determined by solvent extraction of the paper, board or pulp
sample and analysed by gas chromatography with mass selective detection (GC-MS), using diethylnaphthalene as
an internal standard.
NOTE It may be worthwhile to state that diisopropylnaphthalene (DIPN) can be present as a contaminant in pulp, paper
and board. For the time being it cannot be avoided that diisopropylnaphthalene (DIPN) is present when using recovered fibres.
It may be present as either adsorbed onto the test piece or presen
...