Ethanol as a blending component for petrol - Determination of inorganic chloride and sulfate content - Ion chromatographic method

This European Standard specifies an ion chromatographic (IC) method for the determination of the inorganic chloride content in ethanol from 2,0 mg/l to 25,0 mg/l and of the sulfate content in ethanol from 0,9 mg/l to 15,0 mg/l.

Ethanol zur Verwendung als Blendkomponente in Ottokraftstoff - Bestimmung des Gehaltes an anorganischem Chlor und Sulfat - Ionenchromatographie

Diese Europäische Norm legt ein ionenchromatographisches Verfahren für die Bestimmung des anorga¬nischen Chlorgehaltes (Chlorid) in Ethanol im Bereich von 2,0 mg/l bis 25,0 mg/l und des Gehaltes an Sulfat in Ethanol im Bereich von 0,9 mg/l bis 15,0 mg/l fest.
ANMERKUNG   Anorganische Chlorgehalte können von 0,8 mg/l bis 2,0 mg/l und Sulfatgehalte können von 0,4 mg/l bis 0,9 mg/l bestimmt werden. Trotzdem kann die Präzision dafür nicht angegeben werden, da entsprechende Proben mit Chlor  und Sulfatgehalten aus diesen Bereichen nicht Teil des Ringversuchs waren.
WARNUNG — Die Anwendung dieser Europäischen Norm kann den Einsatz gefährlicher Stoffe, Arbeitsgänge und Geräte mit sich bringen. Diese Norm gibt nicht vor, alle mit ihrer Anwendung verbundenen Sicherheitsprobleme anzusprechen. Der Anwender dieser Norm ist dafür verantwortlich, vorher angemessene Maßnahmen zu ergreifen und die Anwendbarkeit einschränkender Vorschriften zu ermitteln.

Ethanol comme base de mélange à l'essence - Détermination de la teneur en chlorures minéraux et en sulfates - Méthode par chromatographie ionique

La présente Norme européenne prescrit une méthode de chromatographie ionique (IC) pour le dosage dans
l’éthanol des chlorures minéraux de 2,0 mg/l à 25,0 mg/l et des sulfates de 0,9 mg/l à 15,0 mg/l.
NOTE La teneur en chlorure minéral peut être déterminée de 0,8 mg/l à 2,0 mg/l, de même celle en sulfate de
0,4 mg/l à 0,9 mg/l. Cependant, la fidélité n’a pas été établie étant donné qu’il n’y avait dans l’essai interlaboratoires aucun
échantillon avec des teneurs en chlorures et en sulfates dans ces intervalles.
AVERTISSEMENT — L'utilisation de la présente Norme européenne peut impliquer l'intervention de
produits, d'opérations et d'équipements à caractère dangereux. La présente Norme européenne n'est
pas censée aborder tous les problèmes de sécurité concernés par son usage. Il est de la
responsabilité de l'utilisateur de consulter et d'établir des règles de sécurité et d'hygiène appropriées
et de déterminer l'applicabilité des restrictions réglementaires avant utilisation.

Etanol kot komponenta za dodajanje motornemu bencinu - Določevanje anorganskega klorida in sulfata - Ionska kromatografska metoda

General Information

Status
Withdrawn
Publication Date
15-Oct-2008
Withdrawal Date
01-Feb-2012
Current Stage
9900 - Withdrawal (Adopted Project)
Start Date
30-Jan-2012
Due Date
22-Feb-2012
Completion Date
02-Feb-2012

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2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.HEthanol comme base de mélange à l'essence - Détermination de la teneur en chlorures minéraux et en sulfates - Méthode par chromatographie ioniqueEthanol as a blending component for petrol - Determination of inorganic chloride and sulfate content - Ion chromatographic method75.160.20Liquid fuels71.080.60Alkoholi. EtriAlcohols. EthersICS:Ta slovenski standard je istoveten z:EN 15492:2008SIST EN 15492:2009en,fr01-januar-2009SIST EN 15492:2009SLOVENSKI
STANDARDSIST EN 15492:20081DGRPHãþD



SIST EN 15492:2009



EUROPEAN STANDARDNORME EUROPÉENNEEUROPÄISCHE NORMEN 15492September 2008ICS 75.160.20Supersedes EN 15492:2007
English VersionEthanol as a blending component for petrol - Determination ofinorganic chloride and sulfate content - Ion chromatographicmethodEthanol comme base de mélange à l'essence -Détermination de la teneur en chlorures minéraux et ensulfates - Méthode par chromatographie ioniqueEthanol zur Verwendung als Blendkomponente inOttokraftstoff - Bestimmung des Gehaltes ananorganischem Chlor und Sulfat - IonenchromatographieThis European Standard was approved by CEN on 4 August 2008.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITÉ EUROPÉEN DE NORMALISATIONEUROPÄISCHES KOMITEE FÜR NORMUNGManagement Centre: rue de Stassart, 36
B-1050 Brussels© 2008 CENAll rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 15492:2008: ESIST EN 15492:2009



EN 15492:2008 (E) 2 Contents Page Foreword.3 1 Scope.4 2 Normative references.4 3 Principle.4 4 Reagents.4 5 Apparatus.5 6 Sampling.6 7 Preparation of calibration solutions.6 8 Preparation of apparatus.7 8.1 Setting up the instrument.7 8.2 Calibration.7 9 Procedure.7 9.1 Sample preparation.7 9.2 Sample analysis.8 10 Calculations.8 11 Expression of results.8 12 Precision.8 12.1 General.8 12.2 Repeatability, r.9 12.3 Reproducibility, R.9 13 Test report.9 Bibliography.10
SIST EN 15492:2009



EN 15492:2008 (E) 3 Foreword This document (EN 15492:2008) has been prepared by Technical Committee CEN/TC 19 “Gaseous and liquid fuels, lubricants and related products of petroleum, synthetic and biological origin”, the secretariat of which is held by NEN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by March 2009, and conflicting national standards shall be withdrawn at the latest by March 2009. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights. The method described in this document is based on a method from a European Regulation on wine [1]. This method has been developed to suit the needs as expressed in the ethanol specification [2], also drafted by CEN/TC 19. This document supersedes EN 15492:2007.
The precision and the range of application for both inorganic chloride and sulfate have been updated based on a interlaboratory study done by CEN/TC 19/WG 27 on "Elemental analysis". Next, only the analytical water grade required has been updated according to general lab practice. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. SIST EN 15492:2009



EN 15492:2008 (E) 4 1 Scope This European Standard specifies an ion chromatographic (IC) method for the determination of the inorganic chloride content in ethanol from 2,0 mg/l to 25,0 mg/l and of the sulfate content in ethanol from 0,9 mg/l to 15,0 mg/l. NOTE Inorganic chloride content can be determined from 0,8 mg/l to 2,0 mg/l and sulfate content can be determined from 0,4 mg/l to 0,9 mg/l. However, the precision was not established as no samples with chloride and sulfate contents in these ranges where included in the interlaboratory test. WARNING — Use of this method may involve hazardous equipment, materials and operations. This method does not purport to address to all of the safety problems associated with its use, but it is the responsibility of the user to search and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN ISO 1042, Laboratory glassware — One-mark volumetric flasks (ISO 1042:1998) EN ISO 3170, Petroleum liquids — Manual sampling (ISO 3170:2004) EN ISO 3696, Water for analytical laboratory use — Specification and test methods (ISO 3696:1987) 3 Principle A test portion of ethanol sample is evaporated on a water bath. The dry residue is dissolved in water. The chloride and sulfate ion contents are determined by comparing the peak area in the chromatogram of the aqueous solution of the test portion with the curve of the calibration standards. The calibration standards are prepared from suitable compounds in aqueous solution. 4 Reagents Use only reagents of recognized analytical grade, such as “IC grade”, unless otherwise specified. 4.1 Sodium chloride (NaCl), MW 58,44 g/mol. 4.2 Sulfuric acid (H2SO4), solution at 0,1 mol/l, of which the concentration is verified by titration, or is certified in case of commercially available product. 4.3 Water, for analytical laboratory us
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