SIST EN ISO 14453:2014

SLOVENSKI STANDARD
SIST EN ISO 14453:2014
01-september-2014
1DGRPHãþD
SIST EN ISO 14453:2000
9ODNQLQH'RORþHYDQMHYDFHWRQXWRSQHVQRYL,62
Pulps - Determination of acetone-soluble matter (ISO 14453:2014)
Faserstoff- Bestimmung acetonlöslicher Bestandteile (ISO 14453:2014)
Pâtes - Détermination des matières solubles dans l'acétone (ISO 14453:2014)
Ta slovenski standard je istoveten z: EN ISO 14453:2014
ICS:
85.040 Vlaknine Pulps
SIST EN ISO 14453:2014 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------

SIST EN ISO 14453:2014

---------------------- Page: 2 ----------------------

SIST EN ISO 14453:2014

EUROPEAN STANDARD
EN ISO 14453

NORME EUROPÉENNE

EUROPÄISCHE NORM
April 2014
ICS 85.040 Supersedes EN ISO 14453:1998
English Version
Pulps - Determination of acetone-soluble matter (ISO
14453:2014)
Pâtes - Détermination des matières solubles dans l'acétone Faserstoff - Bestimmung acetonlöslicher Bestandteile (ISO
(ISO 14453:2014) 14453:2014)
This European Standard was approved by CEN on 15 February 2014.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same
status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2014 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 14453:2014 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------

SIST EN ISO 14453:2014
EN ISO 14453:2014 (E)
Contents Page
Foreword .3

2

---------------------- Page: 4 ----------------------

SIST EN ISO 14453:2014
EN ISO 14453:2014 (E)
Foreword
This document (EN ISO 14453:2014) has been prepared by Technical Committee ISO/TC 6 “Paper, board
and pulps” in collaboration with Technical Committee CEN/TC 172 “Pulp, paper and board” the secretariat of
which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by October 2014, and conflicting national standards shall be withdrawn at
the latest by October 2014.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 14453:1998.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech
Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece,
Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,
Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.
Endorsement notice
The text of ISO 14453:2014 has been approved by CEN as EN ISO 14453:2014 without any modification.

3

---------------------- Page: 5 ----------------------

SIST EN ISO 14453:2014

---------------------- Page: 6 ----------------------

SIST EN ISO 14453:2014
INTERNATIONAL ISO
STANDARD 14453
Second edition
2014-04-01
Pulps — Determination of acetone-
soluble matter
Pâtes — Détermination des matières solubles dans l’acétone
Reference number
ISO 14453:2014(E)
©
ISO 2014

---------------------- Page: 7 ----------------------

SIST EN ISO 14453:2014
ISO 14453:2014(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2014
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
the requester.
ISO copyright office
Case postale 56 • CH-1211 Geneva 20
Tel. + 41 22 749 01 11
Fax + 41 22 749 09 47
E-mail copyright@iso.org
Web www.iso.org
Published in Switzerland
ii © ISO 2014 – All rights reserved

---------------------- Page: 8 ----------------------

SIST EN ISO 14453:2014
ISO 14453:2014(E)

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagent . 1
6 Apparatus . 2
6.1 Option A . 2
6.2 Option B . 2
6.3 Options A and B . 2
7 Sampling and preparation of the sample . 2
8 Procedure. 3
8.1 Extraction with acetone . 3
8.2 Blanks . . 4
8.3 Evaporation of the solvent and drying of the extraction residue . 4
9 Expression of results . 4
10 Test report . 5
Annex A (informative) Precision . 6
Bibliography . 8
© ISO 2014 – All rights reserved iii

---------------------- Page: 9 ----------------------

SIST EN ISO 14453:2014
ISO 14453:2014(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2. www.iso.org/directives
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any
patent rights identified during the development of the document will be in the Introduction and/or on
the ISO list of patent declarations received. www.iso.org/patents
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the meaning of ISO specific terms and expressions related to conformity
assessment, as well as information about ISO’s adherence to the WTO principles in the Technical Barriers
to Trade (TBT) see the following URL: Foreword - Supplementary information
The committee responsible for this document is ISO/TC 6, Paper, board and pulps.
This second edition cancels and replaces the first edition (ISO 14453:1997), which has been technically
revised to include the use of automated extraction, and to add a new precision statement that complies
with the requirements of ISO/TR 24498.
iv © ISO 2014 – All rights reserved

---------------------- Page: 10 ----------------------

SIST EN ISO 14453:2014
ISO 14453:2014(E)

Introduction
The amount of acetone-soluble matter in pulp provides a measure of the content of wood extractives,
often called resin. The acetone-soluble matter includes fatty acids, resin acids, fatty alcohols, sterols,
diglycerides and triglycerides, steryl esters and waxes.
In addition, acetone extracts of mechanical pulps may also contain phenolic compounds such as lignans.
In the case of incompletely washed chemical pulps, the acetone extracts will also include dissolved kraft
lignin.
Metal soaps of fatty and resin acids, such as those present in unwashed or deinked pulp, are not extracted
under the conditions specified in this International Standard.
© ISO 2014 – All rights reserved v

---------------------- Page: 11 ----------------------

SIST EN ISO 14453:2014

---------------------- Page: 12 ----------------------

SIST EN ISO 14453:2014
INTERNATIONAL STANDARD ISO 14453:2014(E)
Pulps — Determination of acetone-soluble matter
1 Scope
This International Standard describes the determination of acetone-soluble matter in pulp.
It is applicable to all types of pulp. The lower limit of the determination is about 0,05 %. This limit can
be lowered by increasing the amount of sample analysed.
2 Normative references
The following documents, in whole or in part, are normatively referenced in this document and are
indispensable for its application. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any amendments) applies.
ISO 7213, Pulps — Sampling for testing
ISO 638, Paper, board and pulps — Determination of dry matter content — Oven-drying method
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
3.1
acetone-soluble matter
amount of material that can be extracted with acetone from a sample of pulp by the method specified in
this International Standard
4 Principle
1)
®
A pulp sample is extracted with acetone in a Soxhlet apparatus (Option A) or in a Soxtec apparatus or
similar extraction equipment (Option B).
®
NOTE Extraction with a Soxtec apparatus is carried out with boiling solvent instead of condensed solvent
®
as is the case with the Soxhlet extraction. The main advantages of the Soxtec system are much shorter extraction
[1] [2]
times and recovery of the main portion of the solvent . Other extraction methods, such as Accelerated Solvent
[2]
Extraction (ASE), can produce different results and are not within the scope of this Internati
...